Here's the definition of CEO from Wikipedia.
A chief executive officer (CEO) or chief executive is one of the highest-ranking corporate officers (executives) or administrators in charge of total management. An individual selected as president and CEO of a corporation, company, organization, or agency, reports to the board of directors.
By definition to be a CEO a couple of things have to be in place. One, there has to be management present, or at the very least employees. Two, there needs to be a formal organization. Three, there has to be a board. If you don't possess these characteristics don't call yourself CEO. Be a founder.